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7.4 LiPo Vs 9.6 NiMh

Those are fairly different batteries. Especially since the voltage difference ist quiet high. If they are the same geometric size you can expect the LiPo battery to have at least the capacity of the NiMH battery. Most likely even something like 50-150% more. The power output will also be a lot higher since LiPo batteries usually allow for higher currents.

But in order to give you more precise information you will have to provide more detailed information on the batteries as well as the use case.
 
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What is your use? There are no Yuneec products that use those voltages.
 

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