Full charge state for either battery should be ~16.6 when read through the ST-16 and between 16.6 and 16.8 when they complete a charge cycle.
Peak voltage is determined by cell count, not mA capacity. Charge rate is determined by mA capacity. If using a programmable after market charger, set it for 4S (4 cell) and at least 5.4 amps (5400 mA) to a maximum of 6.3 (6300 mA) amps. If you set the timer, set it to 1.3 hours. Also set the charger to "balance charge". If you're also using an AC-DC power supply to drive the charger, set the power supply voltage to 16v. A programmable charger terminates the charge cycle when the battery is full when programmed correctly.
If you have been removing batteries from the charger when they hit 15.4v you have been starting out with batteries only half charged.